Alternative Thermal decomposition of group 2 carbonates practical. Magnesium hydroxide: this is the most insoluble and can be brought as a suspension in water. Now let's look at $\ce{SO4^2-}$. Hence, barium hydroxide is more soluble than beryllium hydroxide. Sulphates: Thermal stability The sulphates of group-1 and group-2 metals are all thermally stable. The respective TG- and DSC-curves are represented. This page looks at the solubility in water of the hydroxides, sulphates and carbonates of the Group 2 elements - beryllium, magnesium, calcium, strontium and barium. Attach the delivery tube to the test tube. Hence, more is the stability of oxide formed, less will be stability of carbonates. The same thing applies to the cation while progressing down the group. Thus stability of alkaline earth metal hydroxides decreases with decrease in lattice enthalpy as the size of alkali earth metal cations increases down the group. The solubilities of these salts further increase on descending the group. (ii) All the alkaline earth metals form oxides of formula MO. The thermal stability of the hydrogencarbonates. The least soluble hydroxide in Group 1 is lithium hydroxide - but it is still possible to make a solution with a concentration of 12.8 g per 100 g of water at 20°C. Nitrates of group -1 and group-2 metals are all soluble in water. Even for hydroxides we have the same observations. Decomposition temperatures and decomposition enthalpies of the four hydroxides increase with increasing atomic weight of the compounds. A higher temperature is required to decompose Ba(NO 3) 2 as compared to Mg(NO 3) 2. Since beryllium oxide is high stable, it makes BeCO 3 unstable. Thus stability of alkaline earth metal hydroxides decreases with decrease in lattice enthalpy as the size of alkali earth metal cations increases down the group. BeCO 3 ⇌ BeO + CO 2. The solubility of alkaline metal carbonates and sulphates decreases with decrease in hydration energy as we move down the group. Stability of oxides decreases down the group. 2 M N O 3 h e a t 2 M n O 2 + O 2 The hydroxides. There is no reaction or precipitate when dilute sodium hydroxide is added to a solution of Sr 2+ or Ba 2+ ions. Place the other end of the delivery tube into a test tube which is one third full of limewater. Looking at the enthalpy change of formation for group 2 metal oxides it’s clearly less energy is needed to break them as you go down the group. Although it describes the trends, there isn't any attempt to explain them on this page - for reasons discussed later. ... Solubility of the carbonates increases as you go down Group 1. Correct option: (d) Ba(OH) 2 < Sr(OH) 2 < Ca(OH) 2 < Mg(OH) 2 Explanation: Stability of ionic compounds decreases with decrease in lattice enthalpy. solubility: sulphates of alkali metals are soluble in water. So what causes this trend? Solution: Stability of ionic compounds decreases with decrease in lattice enthalpy. —————————————————— Uses of sulphate and hydroxides. Due to this, the solubility increases with increase in the molecular weight on moving down the group. The size of B e 2 + is smallest and the size of B a 2 + is highest. As the size increases, the decrease in the lattice energy is much more than the decrease in the hydration energy. Charge Density and Polarising Power of Group 2 Metal Cations. On heating alkali metal (Na, K, Rb and Cs) decompose to form metal nitrites and oxygen. (ii) Thermal stability Alkali and alkaline earth metal nitrates decompose on heating. Let's use MgCO 3 as an example. This is why the solubility of Group 2 hydroxides increases while progressing down the group. Place 2 g of a Group 2 metal carbonate in the test tube and reweigh. The increasing thermal stability of Group 2 metal salts is consistently seen. Weigh a test tube. 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